The specter of per- and polyfluoroalkyl substances (PFAS) continues to haunt water treatment professionals. A recent study from North Carolina State University offers a sobering reality: the enduring presence of these “forever chemicals” in groundwater. The research suggests that it could take over 40 years for PFAS to naturally flush out of contaminated groundwater in certain regions, posing a long-term challenge for water quality and public health. 

A Deep Dive into PFAS Persistence 

The study, conducted in North Carolina’s Cumberland and Bladen counties, revealed alarming levels of PFAS in groundwater samples. The detected concentrations of hexafluoropropylene oxide-dimer acid (HFPO-DA) and perfluoro-2-methoxypropanoic acid (PMPA) significantly exceeded the EPA’s maximum contaminant level for HFPO-DA in drinking water. This underscores the urgent need for effective treatment strategies to mitigate the risks associated with PFAS exposure. 

“Even a best-case scenario – without further atmospheric deposition – would mean that PFAS emitted in past decades will slowly flush from groundwater to surface water for about 40 more years,” says David Genereux, professor of marine, earth and atmospheric sciences at NC State and leader of the study. “We expect groundwater PFAS contamination to be a multi-decade problem, and our work puts some specific numbers behind that. We plan to build on this work by modeling future PFAS at individual drinking water wells and working with toxicologists to relate past PFAS levels at wells to observable health outcomes.” 

PFAS Treatment Solutions That Show Promise 

One of the most concerning aspects of PFAS contamination is its persistence. These chemicals are highly resistant to degradation, making them difficult to remove from water sources. Traditional water treatment methods, such as filtration and disinfection, are often ineffective against PFAS. As a result, innovative technologies and advanced treatment processes are required to address this growing challenge. 

Water treatment professionals must consider a range of factors when developing PFAS treatment strategies, including: 

  • Source water characteristics: The specific properties of the source water, such as pH, temperature, and the types of PFAS present, can influence the effectiveness of different treatment methods. 
  • Regulatory requirements: Compliance with stringent regulatory standards for PFAS is essential. Staying updated on the latest regulations and guidelines is crucial. 
  • Treatment costs: The cost-effectiveness of different treatment options must be carefully evaluated, particularly for large-scale applications. 
  • Public health concerns: Prioritizing public health and safety is paramount. Treatment strategies should be designed to minimize exposure to PFAS and protect vulnerable populations. 

Some of the emerging technologies that show promise for PFAS removal include: 

  • Advanced oxidation processes (AOPs): AOPs, such as ozonation and UV-advanced oxidation, can degrade PFAS into less harmful compounds. 
  • Ion exchange: Ion exchange resins can effectively remove PFAS from water, but the spent resins must be properly disposed of. 
  • Granular activated carbon (GAC): GAC can adsorb PFAS, but its capacity is limited, and it may require frequent regeneration or replacement. 
  • Membrane filtration: Membrane filtration technologies, such as nanofiltration and reverse osmosis, can effectively remove PFAS, but they can also produce significant amounts of concentrated brine waste. 

While these technologies offer potential solutions, it is important to note that no single technology is a silver bullet for PFAS removal. A combination of treatment methods may be necessary to achieve optimal results. Additionally, ongoing research and development are essential to identify new and more effective technologies for PFAS remediation. 

As water treatment professionals navigate the complex challenges posed by PFAS, it is imperative to adopt a proactive and collaborative approach. By staying informed about the latest scientific advancements, embracing innovative technologies, and working closely with regulatory agencies and public health officials, we can effectively protect our water resources and safeguard public health for generations to come. 

SOURCES: Environmental Science & Technology, Smart Water Magazine